• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Method and apparatus are disclosed for controlling the relative humidity of a soil environment at a pre-set value using an enclosed volume (6) of a water-soluable or water-swellable material (14), said enclosed volume (6) separated from the external environment by a relatively stiff and strong semipermeable membrane (4) and separated from a pressurized irrigation water supply (36) by a water-impermeable constictable flexible section (8) or diaphragm in the supply line. When the soil is more moist than the pre-set value, intake of water through the membrane (4) causes expansion of the water-swellable material (14) which in turn contricts the flexible section (8) of the water supply line to interrupt the flow of water to the soil. When the soil mixture falls below the pre-set value, egress of water from the water-swellable material (14) releases the constricting force on the flexible section (8) thereby allowing increased flow of water through the flexible section (8) of supply line to the soil.
    公开号:SU1715186A3
    申请号:SU792818159
    申请日:1979-08-31
    公开日:1992-02-23
    发明作者:Орнстейн Леонард
    申请人:Ornstejn Leonard；
    IPC主号:
    专利说明:

    The invention relates to agriculture and can be applied to automatically supply water to the root system of plants, taking into account the optimal moisture consumption for irrigation, for example, pot plants, as well as in irrigation systems in arid areas. In this case, an optimized continuous supply of water to plants in proportion to the moisture and nutrients (mineral fertilizers) consumed by them, dissolved in low concentrations in the feed water, is consumed.
    The purpose of the invention is to increase the reliability and accuracy of humidity control.
    FIG. 1 shows a control valve for implementing the proposed method, based on pinching when expanding a water-swellable material placed in a flexible tube: FIG. 2 - the same with
    unregulated (not adjustable) piston drive: in FIG. 3 - the same, with an adjustable flexible-piston actuator: in FIG. 4 - valve regulator without a flexible tube, made in the form of a seat valve with a piston drive.
    Soil or ordinary soil is a porous absorbed medium with good drainage properties and therefore, with the exception of heavy rain (or irrigation), the plant roots are not submerged in water, but interact with the moist air surrounding them and soil particles, and water is a partition between the gas phase and wet ground. Therefore, one of the most important quality indicators of irrigation can be considered the humidity of the gaseous medium of the soil, which is governed by its skeleton or osmotic potential (the latter is expressed by the pressure in bar).
    When the osmotic potential of a soil changes, an osmotic substance in contact with the soil (placed in the soil with the possibility of contact with its gaseous medium) changes its volume-swells, impregnated with the soil moisture or, on the contrary, dries out. The change in the volume of the osmotic substance, enclosed on both sides of space into a closed volume, causes the displacement of the third spatial side of the closed volume. This movement is used in a known device for changing the flow area of the flexible insert in the pipeline that supplies water for irrigation.
    However, the known devices for implementing this method of regulating water supply to plants, depending on the state of soil moisture, are either cumbersome, using a large mass of swellable material due to the insignificant use of its volume when the state of the material changes from dry to swollen, or insufficiently sensitive. In addition, the porous element is composed of gaskets of ion-exchange membranes characterized by a high degree of swelling. Such ion exchange membranes are usually hydrogel mesh polymers of electrolytic monomers (i.e., they are polyelectrolytes), and although they can swell in distilled water (without ions), mainly due to the mutual repulsion of their fixed charged groups , the degree of their swelling depends not only on the amount of moisture they receive, but also is very sensitive to the amount and type of salts dissolved in water. Such salts neutralize electrostatic repulsion forces. The salt content in the soil moisture varies greatly, so the change in the volume of these porous ionite elements also depends on the salinity and water, which leads to errors in the output of the irrigation rate. In addition, they will irreversibly bind such polyvalent ions from the soil as calcium (Ca and magnesium (Md) and gradually lose most of their ability to swell. Hydrogels (polymer solutions) are less net and consist of substances (for example, polyacrylamide) of uncharged non-ionic polymers, the swelling capacity of which is independent of salts and which can swell only due to changes in soil moisture. The semi-permeable membranes have a porosity large enough to allow free passage of water and salts into the solution polymer or gel. It requires sufficiently small pore sizes to hold the dissolved very large polymer molecules or gel, and therefore, devices based on hydrogels are insensitive to any osmotic pressures that are caused
    0 dissolved salts (if a semi-impermeable membrane will let water through but will not miss the salt).
    The most significant factors for the operability of the method are the substance and properties of the swellable material. With a high concentration, the osmotic potential of the aqueous solution of the long-alkali polymers increases (becomes more than ideal) and the required polymer concentration at a given osmotic potential is lower than the calculated one. Since a cross-linked aqueous gel is one molecule, its molar concentration is infinitely small, and the mole fraction of water is close to unity, regardless of the weight concentration. Therefore, cross-linked gels have very low osmotic pressure at high levels of cross-links, and the less they are, the
    0, the more osmotic behavior of the gels approaches that of an equivalent solution of long chain polymers. Such gels, when contacted with water, swell, reducing the osmotic potential.
    5 significantly faster than simply by increasing the volume of the gel.
    Capillary, surface, adsorption, and osmotic bonding forces of hygroscopic substances, for example
    Hydrogen bonding, as well as the osmotic potential interacting with the solute, reduce the evaporation of soil water into the gas phase of the soil. Thanks to this, even with equilibrium in
    5 wet drained soil with maximum humidity, relative humidity is slightly less than 100%, and the frame potential is about 0.3 bar. When the soil dries, water will first evaporate.
    0 from large capillaries (with a weaker bond), then from small ones, at the same time the frame potential becomes more and more negative, and if it falls to the potential of blowing, the plants may die
    5 (potential at a level of from-10 to-15 bar). For minimum stress and maximum plant growth, the soil moisture potential of the soil should be from -0.3 to -6 bar.
    Thus, the frame potential limits the water availability of the plant root system, therefore, at its established optimal value, different soils (from clay to sand, for example, having very low moisture capacity, can function as efficiently as high-quality soils. A device for determining the relative soil moisture ( according to its framework potential) and to regulate the flow of water according to this indicator in order to maintain a relatively constant framework potential, it works equally well with seven types of plants, and in all types of soil (soil). The method thus involves controlling the relative humidity in the soil surrounding the plant roots by introducing a sensor controller or valve into this zone to regulate the flow of water to this zone to maintain required level of humidity, and the device for implementing this method is an osmotic sensor-regulator of relative humidity, the action of which is based on a change in the volume of the swelling substance enclosed in bemsya and separated from it by a water permeable membrane. Since many crops (e.g., potatoes) need matrix potentials in the order of -0.3 to -0.5 bar to obtain good yields, the materials used in known devices are not very sensitive (e.g., nylon, cellulose fibers, etc.), swell a maximum of 13%. Osmotic swelling of the gels, on the other hand, provides very large changes in volume with small changes in humidity and swell, for example, by a factor of 25 compared to its dry volume when equilibrium of water occurs at 100% relative humidity, when the gel is exposed to matrix potential 0, 3 bar or 99.978% relative humidity.
    To manufacture a compact Dash irrigation valve that overlaps the flow area when the volume of the swelling material changes, it must use a material that works from the valve's closed position at saturation (matrix potential O bar) to the fully open position (at - 0.5 bar ) it is necessary to use a material that will withstand abnormal swelling between wet and dry conditions. Only osmotic solutions or hydrogels with small cross-links can meet this requirement. Since such materials are non-rigid, their use
    it requires structures that are completely different from the known ones, and, in particular, requires semi-impermeable membranes between soluble or swellable material and soil in order to hold the material inside the valve body.
    The pore size of osmotic semipermeable membranes can vary from the size of molecules to microscopic sizes (for example, up to 0.2 mm in diameter), and the class of semiconducting membranes used in the proposed device is well above the limits of pore sizes for heavily perforated structures or for capillaries. (ion-exchange membrane gaskets) and therefore readily differs from the latter in size and structural features, especially the ability to retain material inside the valve body.
    In order to effectively use osmotic solutions and gels in moisture-sensitive valves, it is very important for the swelling material in confined spaces to do this fairly quickly. The reaction rate is largely determined by the diffusion rate of water in the semipermeable membrane and the diffusion rate through the volume of osmotic solution or gel. This leads to the need to use such forms of swellable material, which have a minimum thickness. Since the development of swelling is proportional to thickness, this increases the need for a highly swellable medium (different from those used previously). However, the sensitivity should depend somewhat on the reaction rate (which varies inversely with the square of the thicknesses). The requirement to reduce the thickness also follows from the need to have compact designs that are cheaper and more reliable in operation, but require extremely high swelling (sensitivity).
    The use of osmotic solutions with semipermeable membranes distinguishes the proposed method from the previously known swellable materials for valves that are sensitive to moisture. Hydrogels with insignificant transverse connections, which can swell at least 25 times from their dry volume, sharply distinguish them from liquid solutions and gels, but also more than 100 times greater than the capabilities of most non-ionic materials previously used for such valves.
    In order to implement the method of controlling the relative soil moisture, a closed volume of water with swelling material in
    A sensor controller in which the concentration of this material determines the relative humidity of the soil is separated from it by a semipermeable membrane that is impermeable to water-soluble or water-swellable material but permeable to water. As a result of an osmotic change in volume with a change in the relative soil moisture, the membrane, acting by changing the pressure on the flexible insert (or section) in the water supply pipe, regulates the amount of water flow through the pipe.
    Thus, the proposed method allows the control of the relative humidity of the environment by a predetermined value using a closed volume of water-soluble or water-swellable material at a given concentration. If, for example, moisture as a result of irrigation becomes above a predetermined level, then water penetrates through the membrane into a closed volume, increasing the internal pressure of the material and compressing the flexible section or diaphragm, and reducing the flow of water from the irrigation source. If the soil moisture becomes less than the target, the water is osmotically fed in the opposite direction, the internal pressure in the material drops, the compressive force on the flexible section of the pipeline is removed and the flow of water to irrigate the soil increases. At the same time, the reaction rate of the device is proportional to the ratio of the outer surface area of the membrane to the change in volume required to block the flow of water, as well as proportional to the permeability of the membrane and the hydrogel. Since both of these indicators are quite large, the device reacts (changes the flow area of the flexible insert in the supply pipe) to a change in soil moisture quickly enough and at a not too high flow rate of water.
    The flow of water to irrigate is continuous and smooth.
    Semipermeable membranes used for ultrafiltration and desalting of seawater by means of a reverse osmotic process are suitable for devices that implement the proposed method and pass about every 1 cm area at a pressure drop of 1 atm, and withstand a pressure of several atmospheres.
    The swelling solution is a mixed gel with small transverse bonds, and swelling of the gel does not lead to significant swelling.
    through the pores of the grid, and when a relative water flow occurs in the device, the gel swells inside, which leads to compression of the flexible insert (section) of the pipeline. The most famous gels (gelatin, agarose, etc.) swell less than 10 times compared with their volume in dry form. Most other swellable materials that can be used in
    As the sensitive elements of soil moisture (wood, bark, cellulose, etc.), swell less than 50% of the volume.
    Thus, known swelling substances have a lack of sensitivity.
    It is known that the ability to swell gels increases with a decrease in the density of their cross-links. For example, for use in the proposed method
    0, a cross-linked polyacrylamide gel (with a cross-to-longitudinal bond ratio of 1: 800) is suitable, which is prepared as follows. Solution (A), comprising 0.0125, methi5 lebanisacrylamide, 10.0 g of acrylamide, 7.0 g of glycerol, 1.0 g of urea, 0.08 ml of tetramethylethylene, is dissolved in 50 ml of phosphate buffer (phosphate buffer 0 , 3 m, pH 7.0). The solution is then adjusted to 90 ml.
    0 with further dosage of phosphate buffer. Solution (B) is prepared by dissolving 0.140 g of ammonium persulfate in 10 ml of water. Solutions (A) and (B) are deagized under vacuum for about 10 minutes. Then they
    5 are thoroughly mixed and quickly poured into a mold formed by two glass plates spaced apart by 2 mm. The solution takes a gel form within 5 minutes. After 1 h
    0, the mold opens and the gel, still on one of the mold plates, is dried at 40 ° C for 12 hours.
    The dried flexible gel is removed from the tray, and outer diameter discs (for example 9 mm) for the invented irrigation valve are cut out of the sheet and inserted into the invented valve.
    A piece of such a dried gel with a diameter of 9 mm will have a thickness of 0.25 mm. When immersed in water for 24 hours, its dimensions increase to a new equilibrium value of approximately 18 mm in diameter and 2.5 mm in thickness, which gives an increase in volume
    5 about 40 times compared with dry volume.
    The regulator valve includes a housing 1, which can be assembled from the upper 2 and lower 3 parts (Fig. 4) and is most often cylindrical. A permeable membrane 4 with a pore size of not more than 0.2 mm in diameter is installed on the casing, for which a rigid mesh 5 can be used (Fig. 2-4). Inside chamber L, there is a chamber 6 in which a water-swellable material (hydrogel 7) and a deformable flexible element 8 are placed to change the valve flow area, either in the form of an elastic tube (Fig. 1-3) or in the form of a circular diaphragm (Fig. 4 ). The change in the flow area or hydraulic resistance of the valve when the hydrogel 7 is swollen is made by pressing it on it or by the hydrogel itself on the elastic tube (Fig. 1), or by the piston 9 (Fig. 2-4) moving in the chamber 6. The piston can have a convex pressing pad 10 (figs. 2 and 4) and concave (fig. 3), made at the apex of the cone into which the cylindrical guide surface of the piston passes. In this case, the support platform 11, limiting the movement of the flexible element, can be made either in the form of a rigid flat circular plate 12 (Fig. 2), or in the form of a cone with a smoothed tip, which passes into the cylinder 13 with a screw thread screwed into the lower cylindrical part 3 valve bodies (Fig. 3), or in the form of a conical recess in the latter (Fig. 4).
    From the rest of the valve design elements, it is possible to note the use of nipples 14 for fastening both an elastic tube and the inlet 15 and outlet 16pipelines (FIG. 1-3) or the inlet and outlet openings in the lower part of the housing (FIG. 4).
    When installed in the soil in the zone of the plant root system, the membrane 4, which is highly water permeable and impermeable to hydrogel, freely passes moisture to the latter. The hydrogel under the influence of moisture expands, increasing the pressure in the closed space of the chamber. Increasing the pressure in the internal cavity leads to compression of the flexible insert by directly acting on it with a hydrogel (Fig. 1) or by moving the piston 9 and thereby blocking the water supply for irrigation. As the plant consumes water, the relative humidity around the roots decreases below 99.8%. At the same time, water begins to flow back from the inner cavity of chamber 6 through the membrane into the soil, the pressure in the valve drops, the compression of the flexible insert is relieved, and the flow of water into the soil is restored.
    The flexible elastic tube or diaphragm (FIG. 4) may be made of silicone rubber or other
    materials that are compressible and inert to water (rubber, polyurethane, polyvinyl chloride, etc.), the body can be made of polypropylene, nylon, polyester and
    other materials resistant to water and possessing sufficient mechanical strength. The hydrogel used is a solid gel obtained, for example, from polyacrylamide, polyvinyl alcohol and
    another, able to swell more than 25 times (compared to its dry volume) when it is in equilibrium with water at a humidity of 100%. The semi-permeable membrane can be made in the form of a mesh from
    the same material as the valve body (stainless steel can also be used).
    The threaded connection (Fig. 3) in the lower part of the body allows regulating the soil moisture content, which is required for the development of plants by means of a regulator valve, over a wide range.
    Due to the large area ratio
    the piston to the area of the pressing pads 10 (or the supporting pads in Fig. 3) at the top of the cones; the design options (Figs. 2 and 3) are much less sensitive to pressure changes in the inlet pipe.
    pipeline. In addition, in these embodiments there are no fasteners (nipples) that can be a source of valve failures.
    Thus, the proposed method
    Soil moisture control does not require constant maintenance, is especially convenient when growing pot crops and can be widely used in irrigation systems in arid areas. The method provides continuous optimal supply of water to plants in proportion to the flow rate or moisture and nutrients (mineral fertilizers) dissolved in water. In addition, the method is suitable for controlling humidity and other plant environments other than the soil.
    权利要求:
    Claims (1)
    [1]
    Claims The method of controlling soil moisture, including swelling under the action of soil moisture by an osmotic substance and the effect of the latter on the closure organ by reducing the flow area of the elastic insert in the pipeline,
    moreover, the magnitude of the effect of the osmotic substance on the shut-off organ is regulated by the concentration and volume of the substance with a certain humidity in relation to the volume of the enclosed space in which the substance is located, characterized in that, in order to increase the reliability and accuracy of humidity control, a hydrogel with the ratio of volumes swelled as an osmotic substance f -Lf jcy: T. / J J chuh. X X I t, WW4V DUCT, or at a moisture content of 100% and a dry volume of at least 25: 1 and at most 200: 1, which is separated from the soil by a semi-permeable membrane with a pore size of 0.07-0.2 mm in diameter. F16 fff
    FIG. 7 7 5
    V // 7 /////
    Fig.Z
    类似技术:
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    SU1715186A3|1992-02-23|Method for soil moisture control
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    Peerlkamp et al.1960|Moisture retention by soils
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    同族专利:
    公开号 | 公开日
    AU4477279A|1979-10-18|
    PL213873A1|1979-11-05|
    AU530311B2|1983-07-14|
    DE2967548D1|1986-01-09|
    WO1979000694A1|1979-09-20|
    DD142141A1|1980-06-11|
    EP0004159B1|1985-11-27|
    US4182357A|1980-01-08|
    EG14122A|1983-09-30|
    IL56768D0|1979-05-31|
    CA1104547A|1981-07-07|
    OA06407A|1981-08-31|
    JPS55500270A|1980-05-08|
    EP0004159A1|1979-09-19|
    IN151887B|1983-08-27|
    ES478274A1|1979-12-16|
    MX147749A|1983-01-10|
    ZA79990B|1980-05-28|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    CN103477948B|2013-09-30|2014-10-22|中国农业大学|Irrigation control method and system for saline-alkali soil|
    WO2017083673A1|2015-11-13|2017-05-18|Rain Bird Corporation|Moisture sensing valves and devices|US3204872A|1961-06-12|1965-09-07|Alfred L Whear|Moisture responsive actuator|
    DK103647C|1962-04-03|1966-01-31|Thure Henning Hansson|Apparatus for regulating the supply of liquid to a soil surface, eg in flower pots.|
    US3295088A|1964-10-14|1966-12-27|Johnson Service Co|Electrical humidity sensing element|
    US3426539A|1965-02-02|1969-02-11|Alfred L Whear|Moisture actuated device|
    US3518831A|1967-11-02|1970-07-07|Dawson Inc Alexander|Method and apparatus for subterranean irrigation|
    US3596744A|1968-04-27|1971-08-03|Vladimir Yakovlevich Chesnokov|Coin-testing apparatus|
    US3833013A|1972-04-06|1974-09-03|Baxter Laboratories Inc|Self-valving fluid reservoir and bubble trap|
    DE2325980A1|1973-04-05|1974-10-17|Knut Bertil Edenhorn|DEVICE FOR CONTROLLING THE FLOW OF LIQUID THROUGH A LINE FOR ADDING LIQUID TO A LIQUID-ABSORBING MATERIAL|
    US3898843A|1973-05-22|1975-08-12|Methven & Co Limited G|On-off flow control device and irrigation system incorporating same|
    US3874590A|1973-10-19|1975-04-01|William H Gibson|Moisture responsive apparatus for controlling moisture content of soil|
    DE2513600A1|1975-03-27|1976-10-07|Rainer Ing Grad Schwemmle|Humidity controlled valves for watering systems - with self adjusting valve controlled by sensor whose length varies with humidity|
    US4015616A|1975-08-25|1977-04-05|Hanff Ludovic F|Automatic watering device|
    CH607128A5|1976-03-25|1978-11-30|Elektrowatt Ag|
    US4064086A|1976-07-13|1977-12-20|National Patent Development Corporation|Thermoplastic hydrogels|US4440378A|1981-10-16|1984-04-03|Sullivan Michael P|Flow control apparatus|
    US4655076A|1984-01-23|1987-04-07|Raychem Corporation|Moisture measuring apparatus|
    US4535914A|1984-02-21|1985-08-20|Coty Raymond J A|Automatic larvicide dispenser|
    GB8512813D0|1985-05-21|1985-06-26|Hlp Gardening Products Ltd|Fluid flow control valve|
    US4862701A|1986-09-25|1989-09-05|Nv Raychem Sa|Moisture detection|
    US4805343A|1986-10-20|1989-02-21|Southeastern Illinois College Foundation|Osmotic fiber systems|
    US4938248A|1987-05-04|1990-07-03|Irro-Controls Group|Moisture and pressure sensitive fluid control circuit|
    US4922945A|1987-05-04|1990-05-08|Irro-Controls Group|Self-servicing hydraulic tensiometer with electrical switching and response capabilities|
    DE3733440C2|1987-10-02|1990-09-27|Erwin Sick Gmbh Optik-Elektronik, 7808 Waldkirch, De|
    US5273066A|1988-06-10|1993-12-28|Graham Neil B|Control valves and method of plant growing using flow control|
    GB8813839D0|1988-06-10|1988-07-13|Graham N B|Growing plants|
    WO1991002455A1|1989-08-23|1991-03-07|Emil Richard Smith|Valve apparatus|
    US5186431A|1989-09-22|1993-02-16|Yehuda Tamari|Pressure sensitive valves for extracorporeal circuits|
    FR2657139B1|1990-01-12|1992-07-03|Hutchinson|DEVICE FORMING IRRIGATION CONTROL VALVE, PARTICULARLY FOR POT PLANTS.|
    FR2663193B1|1990-06-14|1993-03-26|Hutchinson|DEVICE FOR GROWING POT PLANTS, WITH LARGE WATER RESERVE.|
    US5329081A|1992-01-17|1994-07-12|Morningside Holdings Pty. Ltd.|Moisture sensor and switch|
    AUPN034294A0|1994-12-30|1995-01-27|Moss Products Pty Ltd|Moisture transducer|
    US5853122A|1996-11-12|1998-12-29|Caprio; Alphonse E.|Relative humidity sensitive irrigation valve control|
    AUPP781798A0|1998-12-21|1999-01-21|Ragless, Clive Lindsay|Matric potential responder improvements|
    AT409552B|2000-04-06|2002-09-25|Oesterr Forsch Seibersdorf|Measuring probe|
    US6220268B1|2000-04-24|2001-04-24|Ross Spencer Bolton|Moisture controlled valve which does not permit partial fluid flow|
    HU0103249A2|2001-08-09|2005-08-29|Emil Richard Smith|Controlled flow limiting equipment|
    US20050087231A1|2003-10-14|2005-04-28|Sanders Larry C.|Non-electronic, automatically controlled valving system utilizing expanding/contracting material|
    GB0516530D0|2005-08-11|2005-09-21|Guest John Int Ltd|Improvements in or relating to liquid flow control devices|
    GB0516532D0|2005-08-11|2005-09-21|Guest John Int Ltd|Improvements in or relating to liquid flow control devices|
    GB0624631D0|2006-12-08|2007-01-17|Brown Michael E|Moisture responsive device and method|
    CN101292621B|2007-04-29|2011-12-07|杨庆理|Long water device, long water device irrlgation system and application of the same in alkaline land improvement|
    US8371325B1|2010-01-25|2013-02-12|Hunter Industries, Inc.|Soil moisture responsive irrigation flow control valve|
    GB2492292B|2010-03-18|2016-10-19|Statoil Petroleum As|Flow control device and flow control method|
    GB201010799D0|2010-06-28|2010-08-11|Smart Tech Ltd|Devices containing swellable material, flow apparatus incorporating such devices and methods of use thereof|
    US10782261B2|2014-03-25|2020-09-22|The Procter & Gamble Company|Apparatus for sensing environmental humidity changes|
    ES2563102B1|2014-09-09|2016-12-27|Ramón Vicente PEREZ ESTEVE|Irrigation transmitter with autonomous hygroscopic control|
    WO2016070005A1|2014-10-31|2016-05-06|Rain Bird Corporation|Soil moisture sensing valves and devices|
    WO2016161992A2|2015-10-13|2016-10-13|中国农业科学院农田灌溉研究所|Novel pressure-less irrigation device|
    WO2018067625A1|2016-10-04|2018-04-12|Lafian Jesse|Tensiometer apparatus and method|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    US05/882,789|US4182357A|1978-03-02|1978-03-02|Method of controlling the relative humidity in a soil environment and apparatus for accomplishing same|
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